Tor protects your network identity, but it does not encrypt the content of your communications at the application layer (beyond the Tor circuit itself). If you send an unencrypted email or message, the content is visible to the exit node (for clearnet connections) or the recipient's server. PGP encryption ensures that only the intended recipient can read your message, regardless of what happens in transit.
PGP also provides authentication through digital signatures. When someone signs a message with their PGP key, you can verify that the message was not altered and that it came from the holder of that key. This is essential in Tor communities where impersonation is a real threat - anyone can claim to be anyone when identities are pseudonymous.
For Tor hidden service operators, PGP is the standard method for proving identity continuity. If your .onion address changes (due to key compromise or server migration), a PGP-signed announcement allows your users to verify that the new address was published by the same entity that controlled the old one.