Signal encrypts your message contents, but the Signal server still sees your IP address, when you are online, and the phone numbers you communicate with. While Signal's protocol minimizes metadata collection through features like Sealed Sender, your ISP can still see that you are connecting to Signal's infrastructure and when you send or receive messages.
By routing Signal through Tor, you prevent your ISP from knowing you use Signal, and you prevent Signal's servers from learning your real IP address. This is particularly important for users in countries where Signal is blocked or where using encrypted messaging tools is itself suspicious and could attract unwanted attention.
Combining Signal with Tor also protects against local network attacks. If you are on a public Wi-Fi network or a network controlled by an adversary, Tor ensures they cannot see your Signal traffic or perform traffic analysis to determine when and how often you communicate.